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There are many methods through which the authenticity of a natural silk fabric can be verified, but the most precise and convincing way is through the burning test. With a lighter or match a piece of silk fabric is ignited, and if there is a burned hair scent present, the intensity of the flame is of medium level, and the ash resulted after the burn is dark black and crumbly, then we have in our hand a fabric made from natural silk.
Another way to test if a fabric is made from natural silk represents the observation of its luster, as it is different from any other fabrics. Natural silk simply shimmers, and that is due to the triangular structure of the silk fibers which allows the fabric to refract incoming light.
Also, if at touch the fabric is extremely smooth, or even feels like a waxed surface, then we're talking about a natural silk fabric, as this characteristic is unique to natural silk.